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Resonance Effect

Which one of ...

Question

Which one of the following is not good way to make ethyl acetate?

C H_{3} C O O H

and

C H_{3} C H_{2} O H

with

H_{2} S O_{4}

as a catalyst

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C H_{3} C O O H

and

C H_{3} C H_{2} O H

with

N a O H

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C H_{3} C O C l

and

C H_{3} C H_{2} O H

with pyridine

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(C H_{3} C O)_{2} O

and

C H_{3} C H_{2} O H

with

H_{2} S O_{4}

as a catalyst

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Solution

The correct option is B $C H_{3} C O O H$ and $C H_{3} C H_{2} O H$ with $N a O H$
Ester doesnt formed in basic medium as NaOH reacts with acid and forms salt as
$C H_{3} C O O H + N a O H \to C H_{3} C O O N a + H_{2} O$
All other forms ester as

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Similar questions

{CH}_{3} {CH}_{2} OH \to_{170^{0} C}^{Conc . H_{2} {SO}_{4}}

{CH}_{3} COOH + C_{2} H_{5} OH \overset{Conc . H_{2} {SO}_{4}}{\to}

CH3COCl+H2------->CH3CH2OH------->CH3CHO(in presence of pd,BaSO4 and quinoline).

Here quinoline acts as what?

a)+ve catalyst

b)catalyst poison

c)promoter

d)medium

C H_{3} C O O H + C H_{3} C H_{2} O H H_{2} S O_{4} - --- \to

H_{2} O

$C H_{3} C O O H + C H_{3} C H_{2} O H \to C H_{3} C O O C_{2} H_{5} + H_{2} O$
This reaction is called as ___ reaction.

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