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Question

Which one of the following is the correct order of -I effect?

A
NR2<OR>F
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B
NR2>OR>F
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C
NR2<OR<F
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D
NR2>OR<F
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Solution

The correct option is C NR2<OR<F
More electronegativity of the attached group with the carbon atom means more it will show -I effect as it has more tendency to withdraw electron.
The correct order of increasing electronegativity of atom is N<O<F and hence the correct order of negative inductive effect is NR2<OR<F i.e. option (c)

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