Which one of the following is the correct order of -I effect?
A
−NR2<−OR>−F
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B
−NR2>−OR>−F
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C
−NR2<−OR<−F
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D
−NR2>−OR<−F
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Solution
The correct option is C−NR2<−OR<−F More electronegativity of the attached group with the carbon atom means more it will show -I effect as it has more tendency to withdraw electron. The correct order of increasing electronegativity of atom is N<O<F and hence the correct order of negative inductive effect is −NR2<−OR<−F i.e. option (c)