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Question

Which one of the following lanthanoids does not form MO2?
(M = Lanthanoid element)

A
Nd
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B
Yb
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C
Dy
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D
Pr
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Solution

The correct option is B Yb
Nd(60)=4f46s2Pr(59)=4f36s2Dy(66)=4f106s2Yb(70)=4f146s2

Yb has fully-filled 4f orbital, it will require very large amount of energy to reach +4 oxidation state. Hence, Yb does not form MO2 type oxide.

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