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Question

Which one of the following mixture is non-ideal solution?

A
Chloroform and acetone
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B
Benzene and toulene
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C
Chlorobenzene and bromobenzene
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D
Bromoethane and chloroethane
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Solution

The correct option is D Chloroform and acetone

The solution formed is nonideal solution with negative deviation from Raoult’s law

Escaping tendencies of both chloroform and acetone decreases as compared to an ideal solution.

The solution exhibit negative deviations from Raoult’s law. This is primary due to more attraction between chloroform and acetone (because of hydrogen bonding as compare to those existing separately between chloroform and acetone molecule) .


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