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Question

Which one of the following mixtures can be separated into pure components by fractional distillation

A
Benzene – toluene
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B
Water – ethyl alcohol
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C
Water – nitric acid
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D
Water – hydrochloric acid
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Solution

The correct option is A Benzene – toluene

Only Benzene-Toluene mixture forms an ideal solution. Rest shows either positive or negative deviation from Raoult's law hence will form Azeotrope which can't be separated by fractional distillation.


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