Which one of the following orders is correct regarding the −I effect of the substituents?
A
−NR2<−OR>−F
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B
−NR2>−OR>−F
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C
−NR2<−OR<−F
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D
−NR2>−OR<−F
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Solution
The correct option is C−NR2<−OR<−F Alkyl is an electron releasing group has +I inductive effect. −F has −I inductive effect. Oxygen is more electronegative than nitrogen. Therefore the order of −I effect is −NR2<−OR<−F