The correct options are
A Saturation of water with CaSO4
C Saturation of water with CaCO3
D Saturation of water with MgCO3
Hard water is water that has high mineral content (in contrast with "soft water"). Hard water is formed when water percolates through deposits of calcium and magnesium-containing minerals such as limestone, chalk and dolomite.
The following processes will produce hard water
1. saturation of water with CaCO3
2. saturation of water with MgCO3
3. saturation of water with CaSO4
Hence options A,B & D are correct.