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Preparations and Reactions of Sodium Oxide

Which one of ...

Question

Which one of the following reactions does not occur during the Solvay's process for the manufacture of $N a_{2} C O_{3}$ ?

N H_{3} + H_{2} O + C O_{2} ⟶ N H_{4} H C O_{3}

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2 N a H C O_{3} Δ - \to N a_{2} C O_{3} + C O_{2} + H_{2} O

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N a C l + C a C O_{3} ⟶ N a_{2} C O_{3} + C a C l_{2}

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2 N H_{4} C l + C a (O H)_{2} ⟶ 2 N H_{3} + C a C l_{2} + 2 H_{2} O

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Solution

The correct option is A $N a C l + C a C O_{3} ⟶ N a_{2} C O_{3} + C a C l_{2}$
The following reactions occur during the Solvay's process for the manufacture of $N a_{2} C O_{3}$ .
(A) $N H_{3} + H_{2} O + C O_{2} ⟶ N H_{4} H C O_{3}$
(B) $2 N a H C O_{3} Δ - \to N a_{2} C O_{3} + C O_{2} + H_{2} O$
(D) $2 N H_{4} C l + C a (O H)_{2} ⟶ 2 N H_{3} + C a C l_{2} + 2 H_{2} O$
The following reaction does not occur during the Solvay's process for the manufacture of $N a_{2} C O_{3}$ .
(C) $N a C l + C a C O_{3} ⟶ N a_{2} C O_{3} + C a C l_{2}$
Ammonia soda process (Solvay's process) is the process for the preparation of sodium carbonate. The raw materials used are $N a C l, N H_{3}$ and $C O_{2}$ .

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