Which one of the following represents the correct ratio of the energy, of electron in ground state of H atom to that of the electron in the first excited state of Li+ ?
A
4 : 9
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B
9 : 4
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C
1 : 4
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D
4 : 1
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Solution
The correct option is A 4 : 9 ∵En∝Z2n2For H atom E1∝1212 [∵Z=1 for hydrogen ] Or E1∝1 For Li+ ion : E2∝(3)2(2)2 [∵z=3 for Li+ ion] Or E2∝94 Thus, E1 (for Harmon) : E2 (for Li+ ion) Or 1:94 or 4:9