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Question

Which one of the following species does not exist under normal conditions?

A
Be2+
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B
Be2
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C
B2
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D
Li2
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Solution

The correct option is D Be2
Be2 does not exist under normal condition. Beryllium has four electrons , so electronic configuration of Be2 having 8 electrons will be σ1s2σ1s2σ2s2σ2s2 and the bond order is
NaNb2=0
Since Be2 is having bond order 0 , no bond is formed between the two atoms. Hence Be2 is unstable

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