The correct option is D BF3
Option (a) - Ca(OH)2. is a base as it releases OH− ions in its aqueous solution => Arrhenius Base
Option(b) - NH3 is a proton acceptor => Bronsted-Lowry Base
Option(c) - HSO−4 is the conjugate base of H2SO4 => Bronsted-Lowry Base
Option(d) - BF3 has no free electrons or OH− to release; rather it has vacant orbitals (2p) which attract electrons. Hence, it behaves as a Lewis acid.