Which one of the following statements is correct in relation to ionization enthalpy?
A
Electron-electron repulsion forces in the outer orbitals of the elements do not affect the ionization enthalpy.
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B
Removal of an electron from orbitals bearing higher 'n' value is easier than from orbitals having lower 'n' value.
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C
The ionization enthalpies of iso-electronic species are same because their size and electron configuration are same.
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D
End of valence electrons is indicated by a small jump in ionization enthalpy.
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Solution
The correct option is B Removal of an electron from orbitals bearing higher 'n' value is easier than from orbitals having lower 'n' value. As the value of 'n' i.e. principal quantum number increases, the size of atom increases and the distance between valence electrons and nucleus increase. As a result, the attraction between the valence electrons and the nucleus decreases. This facilitates the easier removal of valence electrons.