Which one of the following will give a white precipitate with $A g N O_{3}$ in aquous medium ?

[C o (N H_{3})_{5} C l] (N O_{3})_{2}

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[P t (N H_{3})_{2} C l_{2}]

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[P t (e n) C l_{2}]

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[P t (N H_{3})_{4}] C l_{2}

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Solution

The correct option is D $[P t (N H_{3})_{4}] C l_{2}$
A complex which can dissociate $C l^{-}$ in tyhe solution will be able to form white ppt. with $A g N O_{3}$ .Among the given options only complex in option $D$ will be forming the white ppt. as below:
$[P t (N H_{3})_{4}] C l_{2} + 2 A g N O_{3} \to [P t (N H_{3})_{4}] N O_{3} + 2 A g C l$ (White ppt.)

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