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Physical Properties of Alkenes

Which one of ...

Question

Which one of the following would not give butyl acetate when reacted with 1-butanol?

C H_{3} C O C l

(with pyridine)

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C H_{3} C O O H

(with

H_{2} S O_{4}

)

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C H_{3} - C O - O - C O - C H_{3}

(with pyridine)

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C H_{3} C H O

(with

H_{2} S O_{4}

)

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Solution

The correct option is D $C H_{3} C H O$ (with $H_{2} S O_{4}$ )
Aldehyde forms hemiacetals and acetals with alcohols as shown but other options will give butyl acetate as product.

Option D is correct.

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C H_{3} C O O H

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C_{2} H_{2} H g S O_{4} / H_{2} S O_{4} - -------- \to 333 K (X) ⇌ C H_{3} C H O

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