The correct option is D 10 g of water at 80∘C
Let m g of water whose temperature is θ0(>30∘C) and specific heat is 1 cal/g∘C be added to 20 g of water at 30∘C and let θ be the final temperature of the mixture.
So,
m(1)(θ0−θ)=(20)(1)(θ−20)
∴θ=400+mθ020+m
The right hand side is maximum for option (d). Therefore, the correct answer is (d).