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Question

Which option is not true about the following reaction sequence?

A
Both B and D produce carboxylic acid on acidic hydrolysis
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B
Compound D on acidic hydrolysis produce compound C
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C
One of the compounds produced on acidic hydrolysis of D gives a positive test for Tollens'
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D
Compound D produces a compound on reduction with Sn/HCl which reacts with CS2 followed by HgCl2 giving a compound having the smell of mustard oil and a black coloured compound
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Solution

The correct option is D Compound D produces a compound on reduction with Sn/HCl which reacts with CS2 followed by HgCl2 giving a compound having the smell of mustard oil and a black coloured compound




On acidic hydrolysis of D produces formic acid as one of the product which gives a positive test for Tollens'.

Compound D upon reduction with Sn/HCl will produce a 2o amine which does not give the mustard oil test.

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