The correct option is B MnO2
MnO2 is amphoteric oxide. It has Mn in +4 oxidation state. It reacts with acid as well as base.
Mn2O7 is acidic oxide. It has Mn in +7oxidation state (highest oxidation state). It has covalency with covalently bound O atoms.
MnO is basic oxide. It has Mn in +2 oxidation state (low oxidation state). It is ionically bound oxide.