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Question

Which pair below represents isomers ?

A
CH3CH2CH2OH and HOCH2CH2CH2CH3
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B
CH3CH2CH3 and CH3CH2CH2CH3
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C
CH3CH(Cl)CH3 and CH3CH2CH2Cl
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D
CH3COCH3and CH3CH2CH2CHO
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Solution

The correct option is C CH3CH(Cl)CH3 and CH3CH2CH2Cl
Isomers are the compounds having same molecular formula but different properties due to difference in arrangement of atoms. CH3CHClCH3 and CH3CH2Cl both have same molecular formula C3H7Cl Thus they are positional isomers.
In all other options, the molecular formula of the two cmpounds are not same. So, the correct answer is option (c).

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