Which pair gives Cl2 at room temperature ?
Conc. HCl + KMnO4
2KMnO4 +6 HCl → 2KCl +2MnCl2 +5Cl2 +8H2O
The key idea being that the compound reacting with the chloride ion must be a strong enough oxidising agent to change the oxidation state of chlorine from -1 to 0