Which purification technique is used for high boiling organic liquid compound (decomposes near its boiling point )?

Simple distillation

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Steam distillation

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Fractional distillation

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Reduced pressure distillation

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Solution

The correct option is D Reduced pressure distillation
Reduced pressure distillation or vaccum distillation is used for the purification of high boiling organic liquids which decomposes at or below their boiling point.
Hence, option (d) is correct.

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This method is used to purify liquids having very high boiling points and those, which decompose at or below their boiling points.

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