Which reaction can be used for the direct conversion of amides into 1⁰ amine ?

Hoffmann ammonolysis

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Perkin's reaction

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Claissen reaction

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Reduction with LiAlH₄

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Solution

The correct option is D
Reduction with LiAlH₄

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The Conversion of an amide by action of NaOH and $B r_{2}$ to primary amine that has one carbon less than the starting amide is known as Hofmann-Bromamide reaction.

$R - O | | C - N H_{2} B r_{2} + N a O H - ------ \to (o r) N a o B r R - N H_{2} + N a B r + N a_{2} C O_{3}$

The Conversion of an amide by action of NaOH and $B r_{2}$ to primary amine that has one carbon less than the starting amide is known as Hofmann-Bromamide reaction.

$R - O | | C - N H_{2} B r_{2} + N a O H - ------ \to (o r) N a o B r R - N H_{2} + N a B r + N a_{2} C O_{3}$

Q. Which of the following sequence of reactions (reagents) can be used for the conversion of

P h {C H}_{2} {C H}_{3}

into

P h C H = {C H}_{2}

Q. (1) How will you convert an amide into an amine having one carbon less than the starting compound
(2) Name the reaction

Amides may be converted into amines by reaction named after

[CPMT 1974; MP PET 1992; CBSE PMT 1999]

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Which reaction can be used for the direct conversion of amides into 10 amine ?

The correct option is D Reduction with LiAlH4

Which reaction can be used for the direct conversion of amides into 1⁰ amine ?

The correct option is D
Reduction with LiAlH₄