Hell volhard Zelinsky Reaction
When Cl2 or Br2 is react with carboxylic acid in the presence of red phosphorus then a-hydrogen of carboxylic acid is replaced by Cl2 or Br2
CH3COOHAcetic acid Br2→ CH2BrCOOHα−bromo acetic acid
This reaction is known as Hell Volhard Zelinsky reaction.