Which reagent will convert B into A?

R e a g e n t = K N H_{2}

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R e a g e n t = N a / l i q u o r A m m o n i a

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R e a g e n t = B r_{2} / A l c . K O H

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None of these

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Solution

The correct option is B $R e a g e n t = B r_{2} / A l c . K O H$
By Schimdt reaction, $C H_{3} C O O H$ reacts with hydrazoic acid in presence of conc $H_{2} S O_{4}$ to form $C H_{3} N H_{2}$ (Methylamine).

$C H_{3} C O O H$ reacts with $N H_{3}$ to form $C H_{3} C O N H_{2}$ (Acetamide).

Reagent $B r_{2} / A l c o h o l i c K O H$ converts Acetamide into Methylamine.

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