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Question

Which solution would probably have the highest boiling point?

A
0.100 m KOH
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B
0.100 m Na2SO4
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C
0.100 m C6H12O6
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D
0.200 m CaCl2
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E
0.200 m CH3CH2OH
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Solution

The correct option is D 0.200 m CaCl2
0.200 m CaCl2 solution would probably have the highest boiling point.
The elevation in the boiling point is directly proportional to the product i×m where 'i' is vant Hoff's factor and m is the molality of solution. This product is maximum for 0.200 m CaCl2 solution. Hence, it gives maximum boiling point.
Note: 1 molecule of CaCl2 dissociates in aqueous solution to give 3 ions.
Hence,i×m for 0.200 m CaCl2=0.200×3=0.600

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