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Question

Which species in each of the following pairs is better reducing agent under standard state conditions. E0 values are given. Give reasons for your ?

A
K(s)(2.93 V) or Mg(s)(2.36 V)
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B
Co2+(aq)(1.81 V) or In(s)(0.14 V)
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C
Ce3+(aq)(1.61 V) or Ti2+(0.37 V)
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D
Hg(l)(0.86 V) or Ni(s)(0.23 V)
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Solution

The correct option is B K(s)(2.93 V) or Mg(s)(2.36 V)
Reducing agent Based upon reduction potential higher negative value in electro chemical series in A option K and Mg has high negative values of reduction potential.so better reducing agent is K than Mg.

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