Which species in each of the following pairs is better reducing agent under standard state conditions. E0 values are given. Give reasons for your ?
A
K(s)(−2.93V) or Mg(s)(−2.36V)
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B
Co2+(aq)(1.81V) or In(s)(−0.14V)
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C
Ce3+(aq)(1.61V) or Ti2+(−0.37V)
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D
Hg(l)(0.86V) or Ni(s)(−0.23V)
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Solution
The correct option is BK(s)(−2.93V) or Mg(s)(−2.36V) Reducing agent Based upon reduction potential higher negative value in electro chemical series in A option K and Mg has high negative values of reduction potential.so better reducing agent is K than Mg.