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Question

Which statement(s) is/are correct about hydrogen spectrum?

A
Energy of 2nd orbit is different forH11,H21 and H31
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B
Visible spectrum can be obtained in Lyman series and Balmer series
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C
Infrared spectrum is obtained in Paschen, Brackett and Pfund series
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D
Total number of emission lines obtained in Balmer series is n-2,
where n is principal quantum number and n > 2
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Solution

The correct option is D Infrared spectrum is obtained in Paschen, Brackett and Pfund series

1) Since Z=1 for all three isotopes, energy will be the same.

E=13.6Z2n2

2) Lyman series: Ultraviolet

Balmer series: Visible

3) Paschen, Bracket, P fund Infrared

4) Number of spectral lines when an electron jumps from a state n1 to n2 is not n2 but it is

N=(n12)(n11)2

Hence, option C is correct.


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