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Question

Which substance/ion is oxidised and which substance/ion is reduced in the following reaction?
MnO2+4HClMnCl2+2H2O+Cl2.

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Solution

MnO2+4HClMnCl2+2H2O+Cl2.
Oxidised- HCl . The oxidation number of Cl increases from -1 to 0. Thus, Cl itself is oxidised and acts as reducing agent.
Reduced- MnO2 The oxidation number of Mn decreases from +4 to +2. Thus, Mn itself is reduced and acts as oxidising agent.

Note:
Any species that is oxidised acts as reducing agent.
Any species that is reduced acts as oxidising agent.

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