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Question

Which sugar is called invert sugar? Why is it called so?

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Solution

Sucrose is called invert sugar.
Sucrose is dextrorotatory but upon hydrolysis it gives dextrorotatory glucose and laevorotatory fructose. Since the laevorotation of fructose (92.4) is more than dextrorotation of glucose (+52.5), the overall mixture is laevorotatory.

Thus, hydrolysis of sucrose brings about a change in the sign of optical rotation, from dextro (+) to laevo () and the product is named as invert sugar.

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