Which the following is not isostructural with $S i C l_{4}$ ?

P b O_{4}^{3 -}

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N H_{4}^{+}

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S C l_{4}

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S O_{4}^{2 -}

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Solution

The correct option is C $S C l_{4}$
$S i C l_{4}$ is tetrahedral as it has four chlorine atoms attached tetrahedrally where as $S C l_{4}$ has four chlorine atoms and a lone pair on sulfur which makes its structure see-saw and the remaining molecules are having tetrahedral geometry.
So $S C l_{4}$ is not iso structural with $S i C l_{4}$
Hence option $C$ is correct.

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