The correct option is C Copper ion and hydrogen ion
Copper sulphate solution is obtained when copper sulphate salt is dissolved in water. During electrolysis, the copper sulphate salt (CuSO4) dissociates to give Cu2+ and SO2−4 ions. Simultaneously, water also undergoes dissociation to give H+ and hydroxide ion OH− ions.
Hence, Cu2+ and H+ are the cations released during the dissociation.