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Question

Which will make basic buffer ?

A
50 mL of 0.1M NaOH+25 mL of 0.1M CH3COOH
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B
100 mL of 0.1 M CH3COOH+100 mL of 0.1 M NaOH
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C
100 mL of 0.1 M HCl+200 mL of 0.1M NH4OH
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D
100 mL of 0.1 M HCl+100 mL of 0.1 M NaOH
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Solution

The correct option is C 100 mL of 0.1 M HCl+200 mL of 0.1M NH4OH
CH3COOH1) 25 mL×0.1 M=2.5 mmol0+NaOH50 mL×0.1 M=5 mmol2.5 mmolCH3COONa02.5 mmol+H2O
This is basic solution due to NaOH. This is not basic buffer.

CH3COOH2) 100 mL×0.1 M=10 mmol0+NaOH100 mL×0.1M=10 mmol0CH3COONa010 mmol+H2O
Hydrolysis of salt takes place. This is not buffer.

HCl3) 100 mL×0.1 M=10 mmol0+NH4OH200 mL×0.1M=20 mmol10NH4Cl010 mmol+H2O
This is basic buffer.

HCl4) 100 mL×0.1 M=10 mmol0+NaOH100 mL×0.1 M=20 mmol0NaCl010 mmol+H2O
Neutral solution.

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