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Question

Which will make basic buffer solution?

A
50 mL of 0.1 M NaOH + 25 mL of 0.1 M CH3COOH
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B
100 mL of 0.1 M CH3COOH + 100 mL of 0.1 M NaOH
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C
100 mL of 0.1 M HCl + 200 mL of 0.1 M NH4OH
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D
100 mL of 0.1 M HCl + 100 mL of 0.1 M NaOH
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Solution

The correct option is C 100 mL of 0.1 M HCl + 200 mL of 0.1 M NH4OH
Buffer solution is the mixture of a weak acid and its conjugate base, or vice versa.
1.

This is basic solution due to NaOH. This is not basic buffer.

2.

Hydrolysis of salt takes place. This is not buffer.

3.

This is basic buffer solution. It is a mixture of weak base and its conjugate acid at the end of reaction.

4.

This is a neutral solution.

Hence, option (c) is correct.

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