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Question

"While comparison of Li+ and Na+ salts in terms of property of complex formation we found that [Li(NH3)4] exists and Na does not form any complex."
Answer whether the above statement is true or false.
If true enter 1, else 0

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Solution

The statement is true.
While comparison of Li+ and Na+ salts in terms of property of complex formation, we found that [Li(NH3)4] exists and Na does not form any complex.
Because of their low positive charge (+1) and relatively large ionic radii, alkali metal cations have only a weak tendency to react with simple Lewis bases to form metal complexes. Complex formation is most significant for the smallest cation (Li+) and decreases with increasing radius. Complex formation is primarily due to the electrostatic interaction of the metal cation with polar molecules.
Hence, Na doesnot form any such complex.

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