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Question

While doing the experiment of copper voltmeter, in which of the following cases, more amount of copper gets deposited at cathode?

A
2 amperes of electric current is passed for 30 minutes
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B
4 amperes of electric current is passed for 20 minutes
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C
0.5 amperes of electric current is passed for 80 minutes
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D
1.5 amperes of electric current is passed for 30 minutes
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Solution

The correct option is B 4 amperes of electric current is passed for 20 minutes
Amount of copper (W) deposited on cathode is directly proportional to the product of electric current flowing and the time of operation.
WIt
W=zIt where z is constant and known as electrochemical equivalent
(A) : WA=z(2)(30×60)=3600z
(B) : WB=z(4)(20×60)=4800z
(C) : Wc=z(0.5)(80×60)=2400z
(B) : WD=z(1.5)(30×60)=2700z
Thus more amount of copper gets deposit at cathode in experiment B.

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