While Fe3+ is stable, Mn3+ is not stabe in acid solution because:
(Mn3++e−→Mn2+, E∘=1.5 V;O2+4H++4e−→2H2O, E∘=+1.23V;Fe3++e−→Fe2+,E∘=0.77V)
Mn3+ oxides H2O to O2 because the standard reduction potential of (Mn3++e−→Mn2+; E∘=+1.5 V) is greater than that (O2+4H++4e−→2H2O;E∘=+1.23V)