Valence Bond theory encompasses both the formation of covalent bonds and the electronic structure of molecules.
The hypothesis assumes that electrons occupy particular atoms' atomic orbitals inside a molecule and that electrons from one atom are attracted to the nucleus of another atom.
Importance of bonding theory:
According to the valence bond (VB) theory, all bonds are localized bonds created when two atoms donate an electron to one another.
Due to the fact that many atoms form bonds utilizing delocalized electrons, this claim is false.
The VB theory states that there are no unpaired electrons in molecular oxygen.
The forms of covalent compounds are well qualitatively described by VB theory.
In contrast, the Molecular Orbital (MO) hypothesis is useful for comprehending bonds more generally.
Though more challenging to master, it is better at predicting the real properties of molecules than VB theory. Because of the variations in the energy levels of orbitals in the molecule, MO theory actually predicts electron transitions.
Numerous instances show that MO theory has been more accurate.
The creation of covalent bonds and the electronic structure of molecules are both explained by the valence bond theory.
According to the hypothesis, electrons reside in the atomic orbitals of individual atoms inside molecules, and they are drawn to the nuclei of other atoms. When the atoms are at a minimum distance from one another, the electron density starts to generate repulsion between the two atoms.
This attraction grows as the atoms get closer to one another.
It is possible to think of this electron density as what holds the two atoms together in a chemical bond because it is located where the lowest potential energy is gained.