Why are Cu,Ag and Ag included under transition elements even though they contain completely filled d−orbitals in their ground state?
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Solution
These metals in their common oxidation states have incompletely filled d-orbitals. e.g, Cu2+ has 3d10 and Au3+ has 5d8 configuration.
Cu displays two oxidation states (+1, +2). In the +1 oxidation state, an electron is removed from the S-orbital. However, in the +2 oxidation state, an electron is removed from the d-orbital now becomes incomplete (3d9). Hence, it is a transition element.