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Byju's Answer
Standard XII
Chemistry
Methods for Ester Synthesis
Why carboxyli...
Question
Why carboxylic acid does not give reaction of carbonyl group?
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Solution
Because of resonance in carboxtlic acid electrophilicity decreases.
∴
carboxylic acid do not give reaction of carboxyl group.
Also carboxylic acid contains acidic proton that is prone to react first with most of reagent (like
N
a
O
H
,etc)
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Similar questions
Q.
Carboxylic acid does not give friedel-craft Reaction?
Q.
Assertion :Carboxylic acids do not give reactions of
>
C
=
O
group or
−
O
H
group. Reason: Carboxylic acids contain replaceable
H
+
ion.
Q.
Carboxylic acids do not give the characteristic reaction of
>
C
=
O
group because of:
Q.
The reagent which does not give acid chloride on reacting with carboxylic acid is
Q.
(a) Write the chemical reaction involved in Wolff-Kishner reduction.
(b) Arrange the following in the increasing order of their reactivity towards nucleophilic addition reaction:
C
6
H
5
C
O
C
H
3
,
C
H
3
−
C
H
O
,
C
H
3
C
O
C
H
3
(c) Why carboxylic acid does not give reactions of carbonyl group?
(d) Write the product in the following reaction
C
H
3
C
H
2
C
H
=
C
H
−
C
H
2
C
N
1.
(
i
−
B
u
)
2
A
l
H
−
−−−−−−−
→
2.
H
2
O
(e) A and B are two functional isomers of compound
C
3
H
6
O
.On heating with NaOH and
I
2
, isomer B forms yellow precipitate of iodoform whereas isomer A does not form any precipitate. Write the formulae of A and B.
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