Why do metal ion having higher reduction potential reduces first??
Reducing nature depends on the tendency of losing electron or electrons. More the negative reduction potential, more is the tendency to lose electron or electrons. Thus, reducing nature decreases from top to bottom in the electrochemical series. The power of the reducing agent increases as the standard reduction potential becomes more and more negative.
Sodium is a stronger reducing agent than zinc and zinc is a stronger reducing agent than iron.
Element | Zn | Fe | |
Reduction Potential | -2.71 | -0.76 | -0.44 |