Why does hot saturated solution of potassium nitrate forms crystal on cooling?
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Solution
A solution that can not dissolve any more of the solute at a given temperature is called a saturated substance.
The solubility of potassium nitrate increases with an increase in temperature and decreases with a decrease in temperature.
The solubility of potassium nitrate decreases with the fall in temperature. Thus, on cooling a saturated solution of potassium nitrate the excess of it separates from the solution, in the form of crystals.