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Question

Why does solution of chloroform & acetone show negative deviation from Raoult's law?
Illustrate the deviation with the help of diagrams.

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Solution


When acetone & chloroform are mixed together a hydrogen bond is formed between them which increases the intermolecular attraction between them & hence decreases the vapour pressure.
(Refer to Image)

1214438_1127890_ans_2aa074e1c3574a9dba356f3a947be066.PNG

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