The total number of electron in neutral Fe is 26.
The electronic configuration of Fe , Fe2+ and Fe3+ are
Fe: [Ar] 3d6 4s2
Fe2+ : [Ar] 3d6
Fe3+ : [Ar] 3d5
The electronic configuration of Fe3+ is more stable because its 3d orbital is a half-filled orbital. It has extra stability compared to the Fe2+ . Hence, Fe2+ will lose one electron easily to form Fe3+.