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Standard XII
Chemistry
Chemical Properties of Alcohol
Why HClis the...
Question
Why
HCl
is the least reactive towards alcohol?
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Solution
HCl
:
At normal temperature and pressure, Hydrogen chloride
(
HCl
)
is a gas made up of the elements Hydrogen and chlorine.
Hydrochloric acid is the name for a gas solution in water.
It is less reactive toward the alcohol because the chlorine atom is more electronegative and is smaller in size.
When alcohols are treated with
HCl
, they usually undergo a nucleophilic replacement reaction, resulting in the formation of an alkyl halide and water.
In the ethanol,
HCl
should be extremely soluble – almost as soluble as it is in water.
Some sources say that up to 78 parts are soluble at
0
°
C
per 100 parts of ethanol, decreasing to 69 parts at
20
°
C
.
The silver nitrate solution is the best way to test for hydrochloric acid.
In a test tube, apply the silver nitrate solution to the test solution and watch the reaction.
Hydrochloric acid is present when a white precipitate forms.
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