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Hydrogen Bonding

Why in nitrat...

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Why in nitration of phenols major product is ortho while in halogentaion it is para product ?

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Q. Assertion :Anisole on nitration gives ortho and para substituted products. Reason: Ortho and para-substituted products are obtained because it is a Nucleophilic Substitution Reaction.

Read the above assertion and reason and choose the correct option regarding it.

Why C6H5CL forms Ortho, para product but C6H5CCl3 form meta product?

Q. Haloarenes react with halogens in the presence of ferric salt as catalyst to give ortho and para dichloro benzene. Which of the following products predominates in ortho and para isomers in this case?

Q. (i) What is the major mononitration product of

P h - C O O - P h

when it is reacted in a nitrating mixture?
(ii) Which of the following are formed when

P h - C O O H

C H_{3} M g I

Q. Explain why phenol in water or polarprotic give

O - P

tribromo product but in nonpolar medium like

C S_{2} C {C l}_{2}

image ortho or p bromo product?

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