Why is fused calcium chloride or concentrated sulphuric acid is used in a desiccator?
Desiccants:
Calcium chloride
Concentrated sulfuric acid
C2H5OH→H2SO4C2H4+H2O
(a) Write the equation for: (i) the preparation of hydrogen chloride from sodium chloride and sulphuric acid. State whether the sulphuric acid should be concentrated or dilute. (ii) the preparation of ammonia from ammonium chloride and calcium hydroxide. (iii) the reaction of hydrogen chloride with ammonia.
Give reasons for the following :
(a) Sodium hydrogen sulphate is not an acid but it dissolves in water to give hydrogen ions, according to the equation
NaHSO4⇌H++Na+SO2−4
(b) Anhydrous calcium chloride is used in a desiccator.
(a) What is the property of concentrated sulphuric acid which allows it to be used in the preparation of hydrogen chloride and nitric acid? (b) What property of hydrogen chloride is demonstrated when it is collected by downward delivery (upward displacement)? (c) Why is hydrogen chloride not collected over water?
Explain, why fused CaCl2, or conc. H2SO4 is used in a desiccator.