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Question

Why is HCl not used to make the medium acidic in oxidation reactions of KMnO4 in acidic medium?

A
KMnO4 acts as a reducing agent in the presence of HCl
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B
KMnO4 is a weaker oxidising agent than HCl
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C
KMnO4 oxidises HCl into Cl2 which is also an oxidising agent
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D
Both HCl and KMnO4 act as oxidising agents
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Solution

The correct option is C KMnO4 oxidises HCl into Cl2 which is also an oxidising agent
HCl is not used to make the medium acidic in oxidation reactions of KMnO4. The reason is that if HCl is used, the oxygen produced from KMnO4+HCl is partly utilized in oxidizing HCl to Cl2, which itself acts as an oxidizing agent and partially oxidises the reducing agent.

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