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Question

Why is the extraction of copper from pyrites more difficult than that from its

oxide ore through reduction?

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Solution

The Gibbs free energy of formation (ΔfG) of Cu2S is less than that of and. Therefore, H2 and C cannot reduce Cu2S to Cu.

On the other hand, the Gibbs free energy of formation of is greater than that of. Hence, C can reduce Cu2O to Cu.

Hence, the extraction of copper from its pyrite ore is difficult than from its oxide ore through reduction.


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