Why it is more appropriate to write reactions O3(g)+H2O2(l)→H2O(l)+2O2(g)as :O3(g)+H2O2(l)→H2O(l)+O2(g)+O2(g) ?
Also suggest a technique to investigate the path of the above redox reaction.
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Solution
Oxygen is produced from ozone and hydrogen peroxide. Adding reaction (1) and (2) gives reaction as shown. Hence, it is more appropriate to write reaction as O3(g)+H2O2(l)→H2O(l)+O2(g)+O2(g)
O3(g)→O2(g)+O(g) ......1
H2O2(l)+O(g)→H2O(l)+O2(g) ......2
O3(g)+H2O2(l)→H2O(l)+O2(g)+O2(g) .......3 The path of the reactions can be traced by using isotope H2O182 in reaction (b)