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Question

Why it is more appropriate to write reactions O3(g)+H2O2(l)H2O(l)+2O2(g) as :O3(g)+H2O2(l)H2O(l)+O2(g)+O2(g) ?
Also suggest a technique to investigate the path of the above redox reaction.

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Solution

Oxygen is produced from ozone and hydrogen peroxide. Adding reaction (1) and (2) gives reaction as shown. Hence, it is more appropriate to write reaction as O3(g)+H2O2(l)H2O(l)+O2(g)+O2(g)
O3(g)O2(g)+O(g) ......1
H2O2(l)+O(g)H2O(l)+O2(g) ......2
O3(g)+H2O2(l)H2O(l)+O2(g)+O2(g) .......3
The path of the reactions can be traced by using isotope H2O182 in reaction (b)

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