Why longer chain carboxylic acids , say propanoic acid , are more acidic than smaller ones like ethanoic acid in gaseous phase?

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Draw the structures for the following compounds :
(a) Ethanoic acid (b) Propanoic acid

How will you convert

(i) ethanoic acid into methanamine?

(ii) hexanenitrile into 1-aminopentane?

(iii) Methanol to ethanoic acid?

(iv) ethanamine into methanamine?

(v) Ethanoic acid into propanoic acid

(vi) Methanamine into ethanamine?

(vii) nitromethane into dimethylamine?

(viii) propanoic acid into ethanoic acid?

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