Why plants don't absorb nitrogen from the air directly like carbon dioxide and oxygen
Nitrogen is the most essential element for living organisms. Nitrogen is present in the form of proteins, vitamins, cytochromes, nucleic acid and hormones. Hence, nitrogen is the fundamental constituent of nucleic acid which play vital role in regulating metabolism, growth reproduction and heredity.
therefore plants require nitrogen in larger amount and acts as principal macronutrients. Majority of plants can not utilize nitrogen in elemental form (N2) even though it constituent 78% of earth atmosphere.thus plants unable to uptake atmospheric nitrogen (N2) as such.